Shampoo: An introduction to micelles

Okay so you have been asking for a pretty advanced lesson on mixed micelles. I think the best way to explain them is to start off with an explanation on micelles (not mixed ones). We actually make and use micelles probably daily. Here are four questions to help you on and discover!

1. Have you noticed that oil and water do not mix?

Oil will always float to the top of water. Even if you really mix the two, droplets will form but allow it to settle for a few hours and the oil and water will naturally separate. See the diagram below.

2. However have you noticed that when you wash oily dishes with soap, the oil is lifted off?

The reason this happens is due to surfactants ( don't stop reading now, I'll explain!!). A surfactant is a special type of chemical. It has two parts
  • Water loving part - usually refered to as a polar head - you know polar like the ice caps made up of water.
  • Oil loving part - usually referred to as a tail ( or a lipid tail - lipid means oil). See the diagram below!
3. So what is so special about surfactants like SLS?

Surfactants like sodium lauryl sulphate (SLS) can interact with both oils and water. This is really special because it means a chemist can therefore combine oil and water WITHOUT the oil separating from the water. This means the oil can be dissolved in water.

This happens because the surfactant helps create micelles. The diagram below shows you how the SLS arranges itself in a water and oil mixture. It also shows how micelles can be formed.

4. So what is a micelle?

In the simplest system, there are three parts needed make a micelle - oil, water and a surfactant - see the diagram below.

They are special because they allow oil to dissolve in water and this is really useful for shampoo (which I will discuss in more detail tomorrow!).

I hope this was a clear explanation, if you don't understand, give me a shout!!! Tomorrow part 2 , What does all this mean for shampoo?


  1. All of this reminds me of my anatomy and physiology class! Girl, you're a chemist! Thanks so much for the lesson, now I need to figure out how to do this to make a good natural moisturizing cream for my FACE, which is drying out and breaking out too!

  2. Phew, thanks Renee. I'm hoping my explanation can be understood. I tried to make it as clear as possible but this is probably the most scientific post I've ever attempted so I really hope people can easily follow and relate to it.

  3. Very clear Jc! Can't wait for Part 2

  4. Thanks Sarah, double phew!

  5. I was able to follow it, even though in high school I have always been chemically challenged. Thank you! Your blog is what I was craving for, and now that I found it, I am trying to catch up from the beginning :)

  6. Great explanation!
    Love your diagrams. Great job!

  7. I like that you called them by common names "water loving" and "oil loving" instead of their scientific terms, very smooth

  8. gud explaination..thanx

  9. What is an easy way to find part 2? I did a search and it didn't come up. Sorry if this is a stupid question1

    1. I have linked it for you now in the article


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